Abstract
AbstractA (6, 14)‐connected metal‐organic framework (MOF), namely [Co9(μ3‐OH)2(CPT)10(HCOO)6]n (1) [HCPT = 4‐(4‐carboxyphenyl)‐1, 2,4‐triazole], was synthesized using custom‐designed bifunctional triazolate‐carboxylate organic linkers and CoII salts. The framework exhibits two types of highly connected Co3 and Co6 cluster moieties with distinct arrangement, which were generated in situ. The combination of these building units results in an unusual (6, 14)‐connected structure, which has been rarely observed in MOF chemistry. This MOF was characterized by single X‐ray diffraction, PXRD, and TGA. Furthermore, its magnetic properties were investigated.
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