Abstract
Self-assembly of rigid dicarboxylate and flexible N-donor co-ligands in the presence of divalent metal ion affords a new polymer of [Cu(bpea)(bib)]n (1) (bpea = biphenyle-thene-4,4′-dicarboxylate and bib = 1,4-bis(2-methyl-imidazol-1-yl)butane). The structure of 1 exhibits an unusual 2D → 3D motif with sql topology. An interesting 3D polycatenane metal-organic framework was obtained from the assembly of mixed rigid and flexible in the presence of transition metal. The structure reported herein demonstrates that backbone of organic acid play the central role of a structure-directing unit
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
