Abstract
High 'n low: The novel {[Fe(tmphen)2]3[Os(CN)6]2} complex (see structure) is the first example of a cluster in which a high-spin FeIII ion is in a coordination environment of four imine nitrogen atoms and two N-coordinated cyanides. Magnetic studies reveal an unprecedented type of reversible charge transfer induced spin transition (CTIST) between the low-spin FeIINCOsIII and high-spin FeIIINCOsII systems.
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