An unconventional method for measuring the Tc L3-edge of technetium compounds.

Abstract

Tc L3-edge XANES spectra have been collected on powder samples of SrTcO3 (octahedral Tc(4+)) and NH4TcO4 (tetrahedral Tc(7+)) immobilized in an epoxy resin. Features in the Tc L3-edge XANES spectra are compared with the pre-edge feature of the Tc K-edge as well as other 4d transition metal L3-edges. Evidence of crystal field splitting is obvious in the Tc L3-edge, which is sensitive to the coordination number and oxidation state of the Tc cation. The Tc L3 absorption edge energy difference between SrTcO3 (Tc(4+)) and NH4TcO4 (Tc(7+)) shows that the energy shift at the Tc L3-edge is an effective tool for studying changes in the oxidation states of technetium compounds. The Tc L3-edge spectra are compared with those obtained from Mo and Ru oxide standards with various oxidation states and coordination environments. Most importantly, fitting the Tc L3-edge to component peaks can provide direct evidence of crystal field splitting that cannot be obtained from the Tc K-edge.