An ultra-sensitive detection system for sulfur dioxide and nitric oxide based on improved differential optical absorption spectroscopy method.

Abstract

A highly sensitive detection system for sulfur dioxide (SO2) and nitric oxide (NO) was developed via deep ultraviolet differential optical absorption spectroscopy (DUV-DOAS). The wavelength range of 200-230nm was used which was rarely used before as result of severe cross sensitivity to SO2 and NO, in this work, this problem was overcame. A system detection limit (DL) of 60ppb for SO2 has been reached which was among the best ones. Meanwhile, a novel method based on spectrum superposition theory was proposed to decompose the differential optical density (DOD) of NO from that of gas mixture in cross sensitive band. The advantage of this method is that the most sensitive absorption peak of NO was used, which cannot be used by conventional methods due to the cross sensitive to SO2. A system DL of 7ppb for NO has been achieved which is among the best ones reported before. Furthermore, the effect of gas temperature and humidity on concentration retrieval has also been studied, gas temperature and humidity compensation models have also been proposed. The experimental results show that the compensation models succeed in compensating the deviation caused by gas temperature and humidity. The environmental adaptability of the system has been enhanced. This work achieves the aim of monitoring ultra-low concentration of SO2 and NO in a complex environment simultaneously.