An ultra-sensitive optical H2S sensor based on thermal conversion combined with UV-DOAS: Dynamic detection from ppm to ppb level

Abstract

Hydrogen sulfide (H2S) as a common gas plays an important role in both industrial production and clinical pathology. Therefore, the realization of dynamic detection of trace H2S gas is of great significance. In this paper, an ultra-sensitive optical H2S sensor based on thermal conversion and ultraviolet differential optical absorption spectroscopy (UV-DOAS) is developed for dynamic measurement of H2S concentration. The H2S concentration can be derived from the measurement of the change in sulfur dioxide (SO2) concentration before and after conversion. First, the evaluation method of SO2 concentration based on UV-DOAS is presented, and the performance indicators of SO2 concentration measurement are given. Second, the conversion characteristics of H2S under different temperatures and flow rates are investigated, and H2S can be efficiently converted to SO2 in the flowing gas state by controlling the conversion conditions. Finally, the performance indicators of H2S sensor are evaluated. The sensor realizes H2S measurements with a detection limit of 14 ppb * m, while its sensitivity and reliability of measuring H2S concentration increase tenfold, making it suitable for dynamic measurements of trace H2S. In addition, the feasibility of the sensor for applications in atmospheric monitoring and human exhaled breath detection is demonstrated by practical tests.