An oxygen isotope profile in a section of Cretaceous oceanic crust, Samail Ophiolite, Oman: Evidence for δ18O buffering of the oceans by deep (>5 km) seawater‐hydrothermal circulation at mid‐ocean ridges

Abstract

Isotopic analyses of 75 samples from the Samail ophiolite indicate that pervasive subsolidus hydrothermal exchange with seawater occurred throughout the upper 75% of this 8‐km‐thick oceanic crustal section; locally, the H2O even penetrated down into the tectonized peridotite. Pillow lavas (δ18O = 10.7 to 12.7) and sheeted dikes (4.9 to 11.3) are typically enriched in 18O, and the gabbros (3.7 to 5.9) are depleted in 18O. In the latter rocks, water/rock ≤ 0.3, and δ18Ocpx ≈ 2.9 + 0.44 δ18Ofeld, indicating pronounced isotopic disequilibrium. The mineral δ18O values approximately follow an exchange (mixing) trajectory which requires that plagioclase must exchange with H2O about 3 to 5 times faster than clinopyroxene. The minimum δ18Ofeld value (3.6) occurs about 2.5 km below the diabase‐gabbro contact. Although the gabbro plagioclase appears to be generally petrographically unaltered, its oxygen has been thoroughly exchanged; the absence of hydrous alteration minerals, except for minor talc and/or amphibole, suggests that this exchange occurred at T > 400°–500°C. Plagioclase δ18O values increase up section from their minimum values, becoming coincident with primary magmatic values near the gabbro‐sheeted diabase contact and reaching 11.8 in the diabase dikes. These 18O enrichments in greenschist facies diabases are in part due to exchange with strongly 18O‐shifted fluids, in addition to retrograde exchange at much lower temperatures. The δ18O data and the geometry of the mid‐ocean ridge (MOR) magma chamber require that two decoupled hydrothermal systems must be present during much of the early spreading history of the oceanic crust (approximately the first 106 years); one system is centered over the ridge axis and probably involves several convective cells that circulate downward to the roof of the magma chamber, while the other system operates underneath the wings of the chamber, in the layered gabbros. Upward discharge of 18O‐shifted water into the altered dikes from the lower system, just beyond the distal edge of the magma chamber, combined with the effects of continued low‐T hydrothermal activity, produces the 18O enrichments in the dike complex. Integrating δ18O as a function of depth for the entire ophiolite establishes (within geologic and analytical error) that the average δ18O (5.7 ± 0.2) of the oceanic crust did not change as a result of all these hydrothermal interactions with seawater. Therefore the net change in δ18O of seawater was also zero, indicating that seawater is buffered by MOR hydrothermal circulation. Under steady state conditions the overall bulk 18O fractionation (Δ) between the oceans and primary mid‐ocean ridge basalt magmas is calculated to be +6.1 ± 0.3, implying that seawater has had a constant δ18O≈−0.4 (in the absence of transient effects such as continental glaciation). Utilizing these new data on the depth of interaction of seawater with the oceanic crust, numerical modeling of the hydrothermal exchange shows that as long as worldwide spreading rates are greater than 1 km2/yr, 18O buffering of seawater will occur. These conclusions can be extended as far back in time as the Archean (> 2.6 eons) with the proviso that Δ may have been slightly smaller (about 5?) because of the overall higher temperatures that could have prevailed then. Thus ocean water has probably had a constant δ18O value of about −1.0 to +1.0 during almost all of earth's history.