Abstract

An oxygen free polycrystalline 6061 aluminum alloy surface was obtained for the first time in an UHV environment ( 1×10 −9 to 3×10 −9 Torr) after dc ammonia plasma treatment in a separate vacuum system. The specimen was first sputtered and processed in the plasma chamber for about 1 h, transferred after air exposure into the UHV chamber, then cleaned by 2.8 keV Ar + ion bombardment for about 10 min to remove the air-grown oxide. An oxygen free 6061 aluminum surface was observed using Auger electron spectroscopy. Regrowth of the oxide layer in the UHV environment was monitored versus time. A possible cleaning mechanism by the ammonia plasma is proposed. This oxygen free surface is key to achieving thin film growth/deposition on aluminum or its alloys.

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