Abstract

Li-ion batteries have ushered the portable electronics revolution empowering myriads of consumer electronic devices. The bulk Li-ion batteries using liquid organic electrolytes have gone through unprecedented commercial success. In parallel, all-solid-state thin film micro-batteries, employing solid electrolytes, have attracted much interest due to their potential applicationin microelectronic devices. Replacing the liquid electrolytes via solid electrolytes, operational safety can be enhanced while preserving the electrochemical performance. In this spirit, thin films of cathodes, anodes and solid electrolytes can be assembled to fabricate multilayered all-solid-state micro-batteries. The success of this niche sector largely depends on the development and assembly of key electrode and solid electrolyte components. The current review explores a gamut of cathodes, anodes and solid electrolytes for their potential application in all-solid-state thin filmmicro-batteries. © 2019 Indian National Science Academy. All rights reserved.

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