Abstract

Surface plasmon enhancement has been proposed as a way to achieve higher absorption for thin-film photovoltaics, where surface plasmon polariton(SPP) and localized surface plasmon (LSP) are shown to provide dense near field and far field light scattering. Here it is shown that controlled far-field light scattering can be achieved using successive coupling between surface plasmonic (SP) nano-particles. Through genetic algorithm (GA) optimization, energy transfer between discrete nano-particles (ETDNP) is identified, which enhances solar cell efficiency. The optimized energy transfer structure acts like lumped-element transmission line and can properly alter the direction of photon flow. Increased in-plane component of wavevector is thus achieved and photon path length is extended. In addition, Wood-Rayleigh anomaly, at which transmission minimum occurs, is avoided through GA optimization. Optimized energy transfer structure provides 46.95% improvement over baseline planar cell. It achieves larger angular scattering capability compared to conventional surface plasmon polariton back reflector structure and index-guided structure due to SP energy transfer through mode coupling. Via SP mediated energy transfer, an alternative way to control the light flow inside thin-film is proposed, which can be more efficient than conventional index-guided mode using total internal reflection (TIR).

Highlights

  • Energy transfer is a peculiar phenomenon existing in surface plasmon nano-particles [1,2,3], where efficient electromagnetic power is coupled through successive metal particles

  • In contrast to conventional index-guided mode utilizing total internal reflection (TIR), Energy transfer (ET) mediated by surface plasmon uses coupling between nano-particles to achieve waveguiding effect

  • This type of energy transfer using surface plasmon (SP) metal particle as lumped-element transmission line is the phenomenon utilized here to increase light-trapping in thin-film photovoltaics due to its capability to increase in-plane propagation, resulting in large scattering angle and extended photon path length

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Summary

Introduction

Energy transfer is a peculiar phenomenon existing in surface plasmon nano-particles [1,2,3], where efficient electromagnetic power is coupled through successive metal particles. Compared to Received 8 Oct 2012; revised 24 Nov 2012; accepted 3 Dec 2012; published 13 Dec 2012 14 January 2013 / Vol 21, No S1 / OPTICS EXPRESS A132 conventional optical waveguiding with index-guided(IG) mode [22] where total internal reflection (TIR) is used to successively reflect photons back into semiconductor film, surface plasmon (SP) energy transfer(ET) provides larger scattering angle and larger in-plane wavevector component inside device cavity. The in-plane component of photon wavevector is increased inside the semiconductor film, and higher absorbance is achieved due to the phenomenon of surface plasmonic energy transfer between discrete nanoparticles (ETDNP)

Principle of surface plasmon mediated energy transfer
Evolutionary structures for energy transfer
Launching of surface plasmon mode
Angular distribution of plasmon dipole emission
Metallic absorption loss and interface recombination
Findings
Conclusion
Full Text
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