Abstract

We report on the engineering of full thermally activated delayed fluorescence – based white organic light emitting diodes (W-OLEDs) composed of three emitters (2,7-bis(9,9-dimethyl-acridin-10-yl)-9,9-dimethylthioxanthene-S,S-dioxide (DDMA-TXO2), 2,7-bis(phenoxazin-10-yl)-9,9-dimethylthioxanthene-S,S-dioxide (DPO-TXO2) and 3,11-di(10H-phenoxazin-10-yl)dibenzo[a,j]phenazine (POZ-DBPHZ) in two different hosts. By controlling the device design through the study of the emission of DDMA-TXO2 and DPO-TXO2, the behaviour of POZ-DBPHZ in a device with more than one emitter, and the combination of the three materials, respectively, we show that external quantum efficiencies as high as 16% can be obtained for a structure with a correlated colour temperature close to warm white, together with colour rendering index close to 80. However it is in their performance stability that provides the true breakthrough: at 1000 cd/m2 the efficiencies were still above 10%, which is one of the best for this type of devices.

Highlights

  • Citation for published item: Pereira, Daniel and Santos, Paloma and Ward, Jonathan and Data, Pryzemyslaw and Okazaki, Youhei and Minakata, Satoshi and Bryce, Martin and Monkman, Andrew (2017) 'An optical and electrical study of full thermally activated delayed uorescent white organic light emitting diodes.', Scientic reports., 7 (1). p. 6234

  • We report on the engineering of full thermally activated delayed fluorescence – based white organic light emitting diodes (W-organic light-emitting diode (OLED)) composed of three emitters (2,7-bis(9,9-dimethyl-acridin10-yl)-9,9-dimethylthioxanthene-S,S-dioxide (DDMA-TXO2), 2,7-bis(phenoxazin-10-yl)-9,9dimethylthioxanthene-S,S-dioxide (DPO-TXO2) and 3,11-di(10H-phenoxazin-10-yl)dibenzo[a,j] phenazine (POZ-DBPHZ) in two different hosts

  • We successfully combined three different thermally activated delayed fluorescence (TADF) emitters into a white OLEDs (W-OLEDs) structure, and the device’s optical and electrical characteristics were studied in detail

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Summary

Introduction

Citation for published item: Pereira, Daniel and Santos, Paloma and Ward, Jonathan and Data, Pryzemyslaw and Okazaki, Youhei and Minakata, Satoshi and Bryce, Martin and Monkman, Andrew (2017) 'An optical and electrical study of full thermally activated delayed uorescent white organic light emitting diodes.', Scientic reports., 7 (1). p. 6234. A full bibliographic reference is made to the original source a link is made to the metadata record in DRO the full-text is not changed in any way The full-text must not be sold in any format or medium without the formal permission of the copyright holders. It is in their performance stability that provides the true breakthrough: at 1000 cd/m2 the efficiencies were still above 10%, which is one of the best for this type of devices

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