Abstract
Treatment of decacarbonyldimanganese with the alkylarylstannylene RR′Sn ( 2), R=2,4,6- tBu 3C 6H 2, R′=CH 2C(CH 3) 2-3,5- tBu 2C 6H 3, furnishes the tetracarbonyl-stannylmanganese stannylene complex 3, in which the tin atom of the stannyl group is part of a stannaindan ring system. Reaction of 2 with [(OC) 2Fe(NO) 2] yields the tetrahedral iron stannylene complex [OC(NO) 2Fe=SnRR′] ( 4). The structures of 3 and 4 were determined by X-ray crystallography.
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