Abstract
The iridium complex Cp*(PMe3)Ir(Me)(SiMe2OTf) (2) reacts with LiB(C6F5)4(Et2O)2 to form a mixture of the silene complex [Cp*(PMe3)Ir(η2-CH2SiMe2)(H)][B(C6F5)4] (3) and the base-stabilized silylene complex [Cp*(PMe3)Ir(Me)(SiMe2(Et2O))][B(C6F5)4] (4). The silene complex 3 has been crystallographically characterized. Addition of pyridine to this mixture affords Cp*(PMe3)Ir(Me)(SiMe2(L)][B(C6F5)4] (5a, L = pyridine) in good yield, whereas addition of CO or ethylene results in clean formation of Cp*(PMe3)Ir(L)(SiMe3)][B(C6F5)4] (8a, L = CO; 8b, L = C2H4).
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
