Abstract
The structure of ammonium 12-phosphotungstate hydrate, (NH4)3PW12O40·nH2O, was examined by 1H, 2H, 31P, and 15N MAS NMR spectroscopy. The morphology of nanostructured ammonium 12-phosphotungstate was determined from the NMR spectra showing a clear distinction between “bulk” and “surface” ammonium cations in its crystallites. The constants of couplings between the nitrogen (14N, 15N) and hydrogen nuclei (1H) in the crystalline phase were measured for the first time.
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