Abstract
AbstractThe spin–lattice relaxation phenomenon is a good tool for obtaining the thermodynamical parameters of solid metal borohydrides. In the process of deriving the motional parameters from the NMR experimental data, it is very important to adequately interpret the spin–lattice relaxation data. By more precisely considering the quadrupolar interaction of 11B and intermolecular 1H‐1H dipole–dipole interactions, the activation energies and correlation times of the rotational motions of BH4 group in solid magnesium borohydride could be more accurately determined, and the spin–lattice relaxation phenomenon of the quadrupolar nucleus could be more appropriately understood.
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