An NHC-Stabilized H2 GeBH2 Precursor for the Preparation of Cationic Group 13/14/15 Hydride Chains.

Abstract

The synthesis, characterization and reactivity studies of the NHC‐stabilized complex IDipp ⋅ GeH2BH2OTf (1) (IDipp=1,3‐bis(2,6‐diisopropylphenyl)imidazolin‐2‐ylidene) are reported. Nucleophilic substitution of the triflate (OTf) group in 1 by phosphine or arsine donors provides access to the cationic group 13/14/15 chains [IDipp ⋅ GeH2BH2ERR1R2]+ (2 E=P; R, R1=H; R2=tBu; 3 E=P; R=H; R1, R2=Ph; 4 a E=P; R, R1, R2=Ph; 4 b E=As; R, R1, R2=Ph). These novel cationic chains were characterized by X‐ray crystallography, NMR spectroscopy and mass spectrometry. Moreover, the formation of the parent complexes [IDipp ⋅ GeH2BH2PH3][OTf] (5) and [IDipp ⋅ GeH3][OTf] (6) were achieved by reaction of 1 with PH3. Accompanying DFT computations give insight into the stability of the formed chains with respect to their decomposition.