Abstract

This paper proposes a new Gauss–Seidel Bloch formulation of the degenerate eigenvalue problem. The algorithm is designed to be applicable to large vector spaces; it only requires the presence in core memory of the few vectors which constitute the degenerate subspace. The theory is applied to the resonance states of the linear van der Waals complexes I2–X(X=Ar,Ne,He). Partial widths and branching ratios are determined by analyzing the asymptotic outgoing flux transported by the quasibound states in the various open channels. The comparison with previous close-coupling results reveals the efficiency of the method for resolving the resonance eigenvalue problem.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.