Abstract
Coordinative flexibility and ligand bifunctionality play important roles in a biomimetic iron complex of a hexadentate ligand (see picture). This system can bind an auxiliary iodosylbenzene ligand to give the first structurally characterized metal complex of this important oxidizing agent. The complex is a protected precursor for FeVO species, and the selective high-yielding catalytic oxygenation of a sulfide is demonstrated.
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