Abstract

Abstract Three solid phases of (CH3)2NNH3BF4 were found between 200 K and the melting point (415 K) by differential thermal analysis, differential scanning calorimetry, and 1H and 19F NMR measurements. The highest-temperature solid phase obtainable above 268 K was shown to be an ionic plastic phase, where the cations as well as the anions perform rapid translational self-diffusion and overall rotation about their center of gravity.

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