Abstract

AbstractTransient elongational rheology of PP is investigated experimentally. A specifically designed fixture consisting of two drums mounted on a TA Instruments ARES rotational rheometer was used to measure the transient uniaxial extensional viscosity of two commercial grades polypropylene in the molten state. The Hencky strain was varied from 0.003 to 2 s-1 and the temperature was fixed at 180 oC. The measurements show that the steady state elongational viscosity was reached at the measured Hencky strains for polypropylene. Eslami and Grmela have recently introduced a reptation diffusion term arising from the intermolecular chain forces into the rigid FENE-P dumbbells model. The same approach has been used in this study to interpret the transient rheological data in both shear-free and simple shear flows.

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