Abstract

Partial 1100, 1000, 900 and 700 °C isothermal sections of the Al–Rh–Ru phase diagram were determined. The isostructural binary AlRu and AlRh phases probably form a continuous β-range of the CsCl-type solid solutions. The Al 9Rh 2 and C-Al 5Rh 2 dissolve up to 4.5 and 13 at.% Ru, while Al 13Ru 4 and Al 2Ru dissolve up to 14.5 and 8 at.% Rh, respectively. A ternary orthorhombic structure ( Pbma, a = 2.34, b = 1.62 and c = 2.00 nm) related to the Al–Rh ɛ-phases was revealed at the extension of the Al–Rh ɛ-phase area at compositions up to Al 77Rh 15Ru 8.

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