Abstract

An investigation into the wear mechanisms of carbon- and silicon carbide-based refractory materials by silicomanganese alloy

Highlights

  • A study of chemical wear of two carbon-based refractory materials, namely carbon block and carbon ramming paste, in a silicomanganese (SiMn) furnace tap-hole was undertaken by Steenkamp (2014)

  • Thermodynamically, the alloy was not saturated in either C or silicon carbide (SiC), and it was expected that both type K and type SiC refractories would dissolve into the alloy

  • Increasing temperature at a constant Si content of 14.5 mass %, the alloy reached saturation but temperature increases above 1550°C resulted in increased C solubility into the alloy

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Summary

Introduction

A study of chemical wear of two carbon-based refractory materials, namely carbon block and carbon ramming paste, in a silicomanganese (SiMn) furnace tap-hole was undertaken by Steenkamp (2014). Subsequent thermodynamic calculations on alloy compositions from an industrial furnace, using tap data collected over three months, revealed the potential for interaction between the SiMn alloy and refractory being a further source of wear, of the tap-hole refractory and of the hearth refractory. Based on these findings, a further investigation of wear mechanisms of carbon-based refractory material by SiMn alloy on a laboratory-scale was required. Porosity in carbon refractories results from volatile liquids escaping as the mixture is baked, and can create cracks and pores that allow for infiltration of process material (Dzermejko, Baret, and Hubble, 1999)

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