Abstract

Thermal conductivity is one of the most important thermophysical properties of a melt-cast explosive. However, the temperature-dependent thermal conductivity of such explosives cannot be easily measured across the whole solidification process (including the liquid, semi-solid, and solid states). This study used an inverse analysis method to estimate the temperature-dependent thermal conductivity of a 2,4-dinitroanisole/cyclotetramethylenetetranitramine (DNAN/HMX) melt-cast explosive in a continuous way. The method that was used is described here in detail, and it is verified by comparing the estimated thermal conductivity with a prespecified value using simulated measurement temperatures, thereby demonstrating its effectiveness. Combining this method with experimentally measured temperatures, the temperature-dependent thermal conductivity of the DNAN/HMX melt-cast explosive was obtained. Some measured thermal conductivity values for this explosive in the solid state were used for further validation.

Highlights

  • In the manufacturing of melt-cast explosives, a high-temperature suspension of molten explosives begins to cool down until it solidifies at room temperature

  • This study focused on the estimation of the temperature-dependent thermal conductivity of a 2,4-dinitroanisole/cyclotetramethylenetetranitramine (DNAN/HMX) melt-cast explosive during the whole solidification process using an inverse analysis method

  • A Gauss–Newton algorithm was used with an inverse analysis method to estimate the temperature-dependent thermal conductivity of a DNAN/HMX melt-cast explosive with the help of known temperature-dependent density, specific heat capacity, and other thermophysical properties

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Summary

Introduction

In the manufacturing of melt-cast explosives, a high-temperature suspension of molten explosives begins to cool down until it solidifies at room temperature. During this solidification process, there is a significantly inhomogeneous temperature distribution inside the explosive charge and there are notable temperature gradients [1]. There is a significantly inhomogeneous temperature distribution inside the explosive charge and there are notable temperature gradients [1] This could result in severe thermal stress and cause cracking or damage if the mechanical strength of the explosive is not high enough to withstand the resulting forces [2,3]. As a key thermophysical property, thermal conductivity has been widely investigated to enhance the thermal-environment adaptability of brittle materials [4–7]. The temperature-dependent thermal conductivities of materials in their liquid and solid states are generally measured separately using commercially available instruments [10], and the thermal conductivity in the semi-solid state has to be interpolated in some way

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