Abstract

An application of a modified “Ivey Law” to the absorption spectra of the solvated electron in polar solvents is discussed. The transition energy at the maximum of the absorption spectrum of the solvated electron in a particular solvent is a function of a crystal lattice parameter (distance between two hydrogen bonded atoms or negatively polar atoms), dielectric constant and density of the solvent. Intrasolvent and intersolvent correlation of the absorption spectra of the solvated electron has been done.

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