Abstract
The experimental data of Aykan [ J. Catal. 12, 281 (1968)] which reveal a maximum in acrylonitrile yield in ammoxidation of propylene from a m Bi 2O 3 · n MoO 3 catalyst at an m, n value of 1, 2 are reinterpreted in terms of oxidation of Bi 3+ with a consequent increase in the concentration of Mo 5+. The relationship between the m n ratio and Mo 5+ concentration behaves in a manner exactly parallel to the experiental data of Aykan.
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