An Infrared Study of Molybdenum Carbonyl–Butadiene Complexes Encaged in a Zeolite. Implication of the Active Molybdenum Carbonyl Species in the Hydrogenation of Butadiene

Yasuaki Okamoto,Hiroshige Kane,Toshinobu Imanaka

doi:10.1246/cl.1988.2005

An Infrared Study of Molybdenum Carbonyl–Butadiene Complexes Encaged in a Zeolite. Implication of the Active Molybdenum Carbonyl Species in the Hydrogenation of Butadiene

Yasuaki Okamoto, Hiroshige Kane + Show 1 more

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https://doi.org/10.1246/cl.1988.2005

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Journal: Chemistry Letters	Publication Date: Dec 5, 1988
Citations: 7

#Complexes; Mo #Active Species + Show 7 more

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Abstract

Abstract Molybdenum carbonyls encaged in a NaY zeolite were found to form stable butadiene complexes; Mo(CO)4(C4H6) and Mo(CO)2(C4H6)n (n = 1 or 2). These complexes are implied to deactivate the hydrogenation of C4H6 over molybdenum carbonyls/zeolite catalysts. The active species is proposed to be Mo(CO)3 ads.

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