An indirectly coupled open-ended resonator applied to characterize dielectric properties of MgTiO3–CaTiO3 powders

Abstract

The effect of CaTiO3 addition on the complex permittivity of MgTiO3 powder was characterized with an open-ended coaxial cavity resonator in the range of 2.12–3.66 GHz. Permittivities and loss tangents of (1 − x)MgTiO3-xCaTiO3 composite powders with x of 0, 2, 5, and 10 mol. % were measured and compared to theoretical values. Inclusion permittivities and dielectric loss tangents were determined by using Bruggeman symmetric and Looyenga mixing rules and a general mixing model. Additions of CaTiO3 resulted in a clear increase in inclusion permittivities from 13.4 up to 14.9 and in loss tangents from 7.1 × 10−3 up to 8.5 × 10−3. Comparison with the theoretical loss tangent values and quantitative determination of CaTiO3 molar ratios by using measured loss tangents and a general mixing model gave a good correlation. The characterization method was proved to be capable of detecting dielectric changes of MgTiO3–CaTiO3 composite powder and of quantifying the amount of additional substances. This information can be exploited, for example, in the analysis and quality control of different composite powders.