An in Situ Template for the Synthesis of Tunable Hollow Carbon Particles for High-Performance Lithium-Sulfur Batteries.

Abstract

Nanostructured materials with hollow interior voids are gaining great attention due to their fantastic geometries and unique physicochemical properties competent for many applications. However, the development of a fast approach to prepare the hollow structured particles remains challenging. Herein, a new and efficient in situ hard-template method was developed to synthesize hollow carbon nano- and microparticles using the as-prepared SiO2 particles as a hard template directly, without any separation, drying, or redispersion. In this way, the hollow carbon particles with tunable diameters and shell thickness can be synthesized readily, which is simpler and more efficient than the traditional ones. In addition, the universality of this strategy allows us to study the different behaviors of hollow carbon particles in lithium–sulfur batteries when the architectures of hollow particles (i.e., diameter, shell thickness, etc.) were changed. We believe that this in situ method is applicable for synthesizing other core–shell or hollow structured materials (e.g., metal oxide), and also, the high performance of hollow carbon particles in lithium–sulfur batteries and beyond can be further explored.