Abstract
Results are presented for an in situ radiolysis ESR study of simple π and σ radical spin trapping by 2-methyl-2-nitrosopropane (MNP) in dilute aqueous solution. The parent radicals investigated include alkyl radicals (methyl, ethyl, 1-propyl, and 2-propyl), hydroxyalkyl radicals (hydroxymethyl, 1-hydroxyethyl, 1-hydroxypropyl, 2-hydroxy-2-propyl, and 1,2-dihydroxyethyl), nonreducing substituted alkyl radicals (carboxymethyl, 2-hydroxy-2-methyl-1-propyl, and 2-oxo-1-propyl), σ radicals (sulfite, carboxyl, and p-carboxyphenyl), and the radicals produced by radiolysis of water (hydroxyl radical, hydrated electron, and hydrogen atom)
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