An in situ phase transformation induced mesoporous heterointerface for the alkaline hydrogen evolution reaction.

Abstract

The phase structure of a catalyst plays a crucial role in determining the catalytic activity. In this study, a facile phosphorization process is employed to achieve the in situ phase transformation from single-phase Co3O4 to CoO/CoP hybrid phases. Characterization techniques, including XRD, BET, SEM, and TEM, confirm the retention of the mesoporous nature during the phase transformation, forming porous CoO/CoP heterointerfaces. Strong charge transfer is observed across the CoO/CoP heterointerface, indicating a robust interaction between the hybrid phases. The CoO/CoP hybrid exhibits significantly enhanced catalytic activity for the alkaline hydrogen evolution reaction (HER) compared to pristine Co3O4. Density Functional Theory (DFT) calculations reveal that the elimination of the band gap in the spin-down band of Co in CoO/CoP contributes to the observed high HER activity. The findings highlight the potential of CoO/CoP hybrids as efficient catalysts for HER, and contribute to the advancement of catalyst design for sustainable energy applications.