An Improved WMS-2f/1f Spectral Fitting Method Using Orthogonal Test in Initial Parameters Selection.

Abstract

This paper proposes an improved wavelength modulation spectroscopy with the 2nd harmonics normalized by the 1st harmonics (WMS-2f/1f) spectral fitting method using the orthogonal test in selection of the initial parameters. The method is implemented and validated experimentally in measurement of the temperature of diluted H2O in air (1 atm, 291K, 0.7%) by the WMS-2f/1f technique. The transition center wavelength targets near 1344 nm. Results demonstrate that the sum-square-error (SSE) between the calculated and measured WMS-2f/1f spectral profiles decreases significantly within given updating times when the optimized initial parameters are used. Compared to the conventional method, the optimized initial parameters can make the fitting routine converge more efficiently. The temperature of the vapor inferred from the proposed spectral fitting method are in good agreement with the true values.