An improved sequential extraction method to determine element mobility in pyrite-bearing siliciclastic rocks

Abstract

ABSTRACTA sequential extraction method was developed for pyrite-bearing (FeS2) siliciclastic rocks. The focus of this study was to enhance the procedure by an improved oxidation step to completely dissolve not only organic matter but also microcrystalline pyrite. In the first experiment, four oxidation procedures were compared for pure pyrite at extraction temperatures of 25°C and 85°C with hydrogen peroxide (H2O2) as the main oxidant. It was found that pyrite dissolution was most effective by using a mixture of H2O2, ammonium acetate (NH4OAc) and nitric acid (HNO3) at 25°C. This procedure dissolved >90% pyrite, and detected >75% using solute iron measurements. The difference between these two results was explained by reprecipitation of secondary iron minerals. The procedure worked best at 25°C, since solvent evaporation at 85°C amplified iron oversaturation and precipitation. For the pyrite-bearing siliciclastic rocks, two sequential extraction schemes were compared to optimise solid–solvent ratio, extraction step order and type of solvent. Eventually, the most effective step order identified for siliciclastic rocks containing pyrite and little organic matter was to first (1) remove the exchangeable fraction, followed by (2) dissolution with acid and afterwards (3) with a reducing agent. The (4) oxidation step was performed last.