Abstract

A set of P vs. x data for vapor-liquid equilibrium properly contains the pure-component vapor pressures. These values are as uncertain as the values for other measured pressures, and data reduction should yield smoothed values for these as well as for the other pressures. However, the vapor pressures also appear as constants in the reducing equation; here they must have assigned values. This paper shows how the results of data reduction are influenced by different treatments of the vapor pressure.

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