Abstract
The mechanism of unimolecular reaction induced by IR multiple photon absorption (MPA) is discussed experimentally on the basis of branching reac-tion of cyclobutanone and vibrational state analysis of HF formed from fluoroethylenes. It is concluded that the reaction induced by MPA may be interpreted to be close to the one in thermal equilibrium.KeywordsReaction ChannelProduct MoleculeFocus IrradiationUnimolecular ReactionDecomposition Rate ConstantThese keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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