Abstract

To improve the utilization value of electric arc furnace dust (EAFD) containing zinc, the reduction behavior of non-agglomerate dust was investigated with carbon and ferrosilicon in an induction furnace. The experimental results show that when the temperature increases, the zinc evaporation rate increases. When the reducing agent is carbon, zinc evaporation mainly occurs in the range of 900–1100 °C. When the reducing agent is ferrosilicon, zinc begins to evaporate at 800 °C, but the zinc evaporation rate is 90.47% at 1200 °C and lower than 99.80% with carbon used as a reducing agent at 1200 °C. For the carbon reduction, the iron metallization rate increases with a rise in the temperature. When the reducing agent is ferrosilicon, with an increase in temperature, the metallization rate first increases, then decreases, and finally, increases, which is mainly due to the reaction between the metallic iron and ZnO. In addition, the residual zinc in the EAFD is mainly dispersed in the form of a spinel solution near the metallic phase.

Highlights

  • Electric arc furnace dust (EAFD) is one of the by-products of electric furnace steelmaking, and its production accounts for 1~2% of the charging amount of steel scrap and other metal materials [1,2].Because heavy metal elements like lead, chromium, and cadmium are contained in electric arc furnace dust (EAFD), these kinds of by-products are classified as toxic waste by many countries [3]

  • Because heavy metal elements like lead, chromium, and cadmium are contained in EAFD, these kinds of by-products are classified as toxic waste by many countries [3]

  • When carbon is used as the reducing agent, the evaporation of zinc mainly occurs in the temperature range of 900–1100 ◦ C

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Summary

Introduction

Electric arc furnace dust (EAFD) is one of the by-products of electric furnace steelmaking, and its production accounts for 1~2% of the charging amount of steel scrap and other metal materials [1,2]. Because heavy metal elements like lead, chromium, and cadmium are contained in EAFD, these kinds of by-products are classified as toxic waste by many countries [3]. Dust that contains iron, lead, zinc, and chromium can be used as a secondary resource. The recovery of these resources plays an important role in environmental protection [4,5,6,7]. The zinc content of EAFD is generally

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