Abstract
Chloryl chloride, ClClO 2 , isolated in cryogenic matrices is subjected to photolysis, producing chlorine chlorite, ClOClO, which in turn is converted into dichlorine peroxide, ClOOCl. ClOClO is also formed by the reactions Cl+ OClO and ClOCl+0. The products are identified by means of FTIR spectroscopy using 35/37 Cl and 16/18 O isotopic shifts, with the aid of vibrational spectra of related molecules and results of ab initio calculations. The thresholds for photodecomposition of ClOClO, ClClO 2 , and ClOOCl isolated in an argon matrix are above wavelengths of 665, 610, and 360 nm, respectively. Two dissociation channels are observed for both ClOClO and ClOOCl
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