An experimental investigation on the oxidative desulfurization of a mineral lubricant base oil.

Abstract

In the present study, the oxidative desulfurization (ODS) of Sn 650 base oil with total sulfur content of 10,000 ppmw has been investigated experimentally. The response surface methodology (RSM) considering Box-Behnken design (BBD) was applied to examine the impacts of the oxidation temperature (30-70˚C), hydrogen peroxide to sulfur molar ratio (2-8), and formic acid to sulfur molar ratio (20-60) on the sulfur removal. In the next step, the appropriate values of the independent variables such as stirrer speed (750-1250rpm), reaction time (60-180min), and the number of extraction stages (1-4) were determined based on the optimal result obtained from the BBD. The best performance of the ODS process was found at a reaction temperature of 58˚C, an oxidant to sulfur molar ratio of 7.35, a formic acid to sulfur molar ratio of 58.5, a reaction time of 150min, and a stirrer speed of 1250rpm for the oxidation reaction. The achieved sulfur removal after oxidation followed by liquid-liquid extraction was 32 %, and 60 % for one extraction and three extraction stages, respectively. The changes in the base oil specifications after the ODS treatment were also investigated.