Abstract

An investigation of the saturated vapor pressure for the solutions of propane in the two type of industrial compressor oils ProEco®RF22S and RENISO SP46, also as in oil ProEco®RF22S containing fullerene C60 6.837·10-4kg·kg-1is presented in this paper. The measurement of the saturated vapor pressure was conducted using a static method in a temperature range (273…333) K and thepropanemass fraction (0.11…0.595) kg·kg-1.
 An analysis revealed that the expanded uncertainties of the measured saturated vapor pressure do not exceed 0.0419·105Pafor solutionpropane/ProEco®RF22S,0.0716·105Pa for solution propane /RENISO SP46, and 0.0095·105Pa for solution propane/ProEco®RF22 Scontaining C60.The temperature and concentration dependences of the saturated vapor pressure for the object of study have been discussed. The excess of saturated vapor pressure for the solution of propane in oil ProEco®RF22S over the pressure of the solution of propane in oil RENISO SP46 reaches 1.5 105 Pa at a temperature of 330 K and propane fractionof 0.1 kg·kg-1. This effect decreases with temperature decreasing and propane fraction increasing.It was proven that the additive of the fullerene C60 increase the saturated vapor pressure of the solution propane/ProEco® RF22S up to 0.4·105Pa at low temperature and low propane mass fraction insolution. 
 The results obtained proved the expediency of the introduction in the industry the solution of propane/compressor oil ProEco® RF22Scontaining the fullerene C60 as working fluid of vapor compression refrigeration system. The ability of C60additive in oil to increase the saturated vapor pressure of considered working fluid will contribute to increasing the energy efficiency of refrigeration systems.

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