Abstract
A double-charge-transfer spectroscopy study of hydrogen sulphide has been carried out, and six double-ionization energies to various electronic states of H 2S 2+ measured. Because of the conservation of spin multiplicity in the double-charge-transfer reactions which are central to this type of spectroscopy, and the use of OH + as the projectile ion, triplet states of H 2S 2+ were populated. This was confirmed by the good agreement between the measured double-ionization energies and published calculated values for transitions to triplet states of H 2S 2+.
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