Abstract
Inelastic electron tunnelling spectra were obtained for some silanes with CC bonds doped from solution in acidic aqueous alcohol and from their vapours. Spectra show a high level of hydrolysis of the silanes doped from solution, but only partial hydrolysis from vapour doping. Vinyltrichlorosilane is fully hydrolysed with both methods of doping. A silane containing a methacrylate group is partially saponified.
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