An Evaluation of Procedures Used in Computing Chemical Denudation Rates

Abstract

Computations of chemical denudation rates (that is, the average rate of lowering of the earth9s crust by chemical processes) should be based only upon those components of dissolved loads of streams that are derived from chemical weathering of rocks and soils, even though identification of those components is difficult and imprecise. Past computations of chemical denudation rates exaggerated by 1.4 to 2.4 times the significance of this process because they were calculated from total dissolved loads. Identification of separate denudation and nondenudation components in a water analysis can be done most readily for streams in crystalline silicate rock terrane where commonly 25 to 55 percent of the dissolved solids are HCO 3 −1 , SO 4 −2 , Cl −1 , and NO 3 −1 that cannot be derived from the underlying rock; instead these ions are derived either directly from the atmosphere or from atmosphere-biosphere interactions. Most of the remaining solutes are derived from chemical weathering or rainfall, or both. Existing data are often insufficient to separate these two components, but atmospheric contributions to dissolved loads of dilute natural waters are substantial. The commonly observed increased concentration of dissolved solids in chemically polluted rivers is produced by concentration of natural dissolved loads by evaporation, and by addition of solutes not present in natural waters. Concentration of natural solutes represents a modification of natural denudation processes that does not change the rate of denudation. Addition of new solutes represents man-induced, accelerated chemical denudation. Extrapolation of modern chemical denudation rates to geologic situations is extremely imprecise because of uncertainties in assessing man9s influence on present dissolved loads, in reconstructing the number and magnitude of past climatic changes, and in evaluating the effects of evolving flora and fauna.