An Ethynylene-Bridged Pentacene Dimer: Two-Step Synthesis and Charge-Transport Properties.

Abstract

A rigid and planar ethynylene-bridged pentacene dimer (PenD) was synthesized from pentacenequinone in two steps, skipping the conventional stepwise approach. A brickwork motif in the single crystal shows two-dimensionally extended electronic interaction in the solid state. Highly crystalline dip-coated films exhibited average hole mobility of 0.24 cm2 V-1 s-1 , comparable to that of the single-crystal organic field-effect transistors. This discovery and understanding of the reaction for the facile synthesis of ethynylene-bridged π-conjugated systems enables to the synthesis of a wide range of organic semiconducting materials.