Abstract
In egg lecithin-water lameliar phases, spin-labeled stearic acid gives two superimoposed ESR spectra which are only well resolved when the temperature is >30°. These two spectral components are attributed to the dissociated and non-dissociated forms of the fatty acid carboxylic group, anchored at two different positions in the polar interface constituted by the hydrated lipid polar heads. Results on such interactions of other functional groups (spin-labeled fatty ester and fatty alcohol) are also presented.
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