Abstract
A new lanthanide-organic framework incorporating both substituted isonicotinic acid and oxalate coligand has been fabricated successfully through solvo-thermal reaction, namely, {[Er(μ2-H2Minca)](μ2-C2O4 · 2H2O] · 2H2O}n (I) (H3Minca = 2-(hydroxyl)-6-methyl-isonicotinic acid, H2C2O4 = oxalate acid). Complex I exhibits two dimensional (2D) corrugated networks with a 63 topology, in which {LnO8} polyhedron units are alternately linked through carboxylate and oxalate oxygen atoms into the 2D sheet layer (CIF file CCDC no. 948026). Thermogravimetric and different thermal analysis measurements indicate that I displays high thermal stability. Complex I also shows characteristic f-f transition luminescence emission in NIR region.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
