Abstract

AbstractA conductive blend of polyaniline (PANI) with sodium form poly(methyl methacrylate‐co‐acrylic acid) copolymer (PMMAA) was prepared by in situ dispersion polymerization. The PANI‐PMMAA blends were characterized with UV–vis, FTIR, and electron paramagnetic resonance (EPR) spectra. The effects of PANI and temperature on the electronic properties of the PANI‐PMMAA blends were studied with EPR technique. The PANI and temperature affect the intermolecular interaction between PANI and PMMAA and then determines the EPR parameters (A/B ratio, g factor, T2, ΔHpp, Ns, and lineshape). POLYM. COMPOS., 2008. © 2008 Society of Plastics Engineers

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