Abstract
Purpose This paper aims to improve the corrosion resistance of AH36 carbon steel, an epoxy resin (EP)-based superhydrophobic coating was prepared on the surface of AH36 carbon steel. Design/methodology/approach The hydroxylated multi-walled carbon nanotubes were used as nanocontainers, and the corrosion inhibitor L-proline was loaded by negative pressure method and then modified it with 3-aminopropyltriethoxysilane and 3-mercaptopropyltrimethoxysilane, got functionalized hydroxy carbon nanotubes (KH-CNTs@LP). The KH-CNTs@LP was mixed with the EP, and the KH-CNTs@LP/EP superhydrophobic coating was successfully prepared on the surface of the AH36 carbon steel matrix by spraying. Findings The results showed that the water contact angle of the KH-CNTs@LP/EP superhydrophobic coating is 155.2° and the rolling angle is 5°. The KH-CNTs@LP/EP superhydrophobic coating had a good corrosion resistance in the pH = 4 corrosion environment, |Z|0.01 Hz was 7.21 × 107 Ω·cm2. Originality/value The KH-CNTs@LP/EP superhydrophobic coating is pH-responsive and releases L-proline, which increased the impedance of the coating and can effectively improve the protection efficiency of the coating on the metal. The active protection is provided by loaded L-proline inhibitor from KH-CNTs@LP, whereas the passive protection is achieved through the water rejection of superhydrophobic surfaces.
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