An Enlarged Canonical Quantization Scheme and Quantization of a Free Particle on Two-Dimensional Sphere

Abstract

For a non-relativistic particle that freely moves on a curved surface, the fundamental commutation relations between positions and momenta are insufficient to uniquely determine the operator form of the momenta. With introduction of more commutation relations between positions and Hamiltonian and those between momenta and Hamiltonian, our recent sequential studies imply that the Cartesian system of coordinates is physically preferable, consistent with Dirac' observation. In present paper, we study quantization problem of the motion constrained on the two-dimensional sphere and develop a discriminant that can be used to show how the quantization within the intrinsic geometry is improper. Two kinds of parameterization of the spherical surface are explicitly invoked to investigate the quantization problem within the intrinsic geometry.