Abstract
We report herein the first complex of a selenium coronand, namely, (1,5,9,13-tetraselenacyclohexadecane) copper (II) trifluoromethanesulfonate, [Cu(16Se4)]-[SO 3 CF 3 ] 2 and its spontaneous electron-transfer reaction in organic solvents to give Cu(I) as well as the intermediate radical cation [16Se4] •+ and the stable dication [16Se4] 2+
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