An electron spin echo study of the photoexcited triplet state of tetracene in p-terphenyl crystals at room temperature

Abstract

Room temperature magnetic resonance studies of the photoexcited triplet state of tetracene in p-terphenyl crystals have been carried out by the electron spin echo technique. The studies yield the following structural and dynamical information: (1) zero-field splittings; D/hc=±0.0551(1) and E/hc=∓0.0042(1) cm−1; (2) spin densities: ρ1(α)=0.055, ρ2(β)=0.016, ρ5(γ)=0.217, ρ13=−0.025, and ρ15=−0.027; and (3) relative triplet population rates: px≊py≳pz.