Abstract
A large number of substituted phenoxymethyl radicals formed by the reaction of t-butoxyl radicals with substituted anisoles, thioanisole, phenetole, and thiophenetole have been investigated by e.s.r. The methylene hyperfine couplings are only slightly dependent on the nature of substituents in the aromatic ring; in all cases coupling to ring protons and fluorine atoms has been resolved. The methylene couplings of several of the radicals exhibit linewidth alternation at –35°. Evidence is presented for long-range coupling to ring atoms when ortho-substituents force the methylene group out of the plane of the aromatic system.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society B: Physical Organic
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
